JEE Main Chemical Bonding & Molecular Structure Practice Questions With Solutions

Updated By Diksha Sharma on 07 Jan, 2025 21:16

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JEE Main Chemistry Chemical Bonding & Molecular Structure Practice Questions

Question 1.

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The correct increasing order for bond angles among BF3,PF3 and ClF3 is :

Question 2.

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In which one of the following pairs the central atoms exhibit sp2 hybridization ?

Question 3.

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The shape of carbocation is :

Question 4.

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When ฯˆA and ฯˆB are the wave functions of atomic orbitals, then ฯƒโˆ— is represented by :

Question 5.

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Match List I with List II

LIST I
(Molecule)
LIST II
(Shape)
A.NH3I.Square pyramid
B. BrF5II.Tetrahedral
C.PCl5III.Trigonal pyramidal
D.CH4IV.Trigonal bipyramidal

Choose the correct answer from the options given below:

Question 6.

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Match List I with List II

LIST I
(Compound/Species)
LIST II
(Shape/Geometry)
A.SF4I.Tetrahedral
B. BrF3II.Pyramidal
C.BrO3โˆ’III.See saw
D.NH4+IV.Bent T-Shape

Choose the correct answer from the options given below:

Question 7.

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Match List I with List II

LIST I
(Molecule/Species)
LIST II
(Property/Shape)
A.SO2Cl2I.Paramagnetic
B. NOII.Diamagnetic
C.NO2โˆ’III.Tetrahedral
D.I3โˆ’IV.Linear

Choose the correct answer from the options given below:

Question 8.

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Match List I with List II.

LIST I
LIST II
A.IClI.T - shape
B.ICl3II.Square pyramidal
C.ClF5III.Pentagonal bipyramidal
D.IF7IV.Linear

Choose the correct answer from the options given below :

Question 9.

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Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : NH3 and NF3 molecule have pyramidal shape with a lone pair of electrons on nitrogen atom. The resultant dipole moment of NH3 is greater than that of NF3.

Reason (R) : In NH3, the orbital dipole due to lone pair is in the same direction as the resultant dipole moment of the Nโˆ’H bonds. F is the most electronegative element.

In the light of the above statements, choose the correct answer from the options given below :

Question 10.

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Number of ฯƒ and ฯ€ bonds present in ethylene molecule is respectively :

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Question 1.

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The correct statement/s about Hydrogen bonding is/are

A. Hydrogen bonding exists when H is covalently bonded to the highly electro negative atom.

B. Intermolecular H bonding is present in o-nitro phenol

C. Intramolecular H bonding is present in HF.

D. The magnitude of H bonding depends on the physical state of the compound.

E. H-bonding has powerful effect on the structure and properties of compounds

Choose the correct answer from the options given below:

Question 2.

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The number of species from the following that have pyramidal geometry around the central atom is _________

S2O32โˆ’,SO42โˆ’,SO32โˆ’,S2O72โˆ’

Question 3.

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Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is ________.

NO3โˆ’,BCl3,ClO2โˆ’,ClO3โˆ’

Question 4.

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Which one of the following molecules has maximum dipole moment?

Question 5.

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Given below are two statements :

Statement (I) : A ฯ€ bonding MO has lower electron density above and below the inter-nuclear axis.

Statement (II) : The ฯ€โˆ— antibonding MO has a node between the nuclei.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 6.

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Select the compound from the following that will show intramolecular hydrogen bonding.

Question 7.

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Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): PH3 has lower boiling point than NH3.

Reason (R) : In liquid state NH3 molecules are associated through vander Waal's forces, but PH3 molecules are associated through hydrogen bonding.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 8.

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Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O,N2,SO2 and ClF3 :

Question 9.

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Which of the following is least ionic?

Question 10.

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The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals

A. have the same energy

B. have the minimum overlap

C. have same symmetry about the molecular axis

D. have different symmetry about the molecular axis

Choose the most appropriate from the options given below:

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