JEE Main Thermodynamics Practice Questions With Solutions

Updated By Diksha Sharma on 07 Jan, 2025 21:16

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JEE Main Chemistry Thermodynamics Practice Questions

Question 1.

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Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason (R)

Assertion (A) : Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always 57kJmol1

Reason (R) : Enthalpy of neutralisation is the amount of heat liberated when one mole of H+ ions furnished by acid combine with one mole of OH ions furnished by base to form one mole of water.

In the light of the above statements, choose the correct answer from the options given below.

Question 2.

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Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following :

Question 3.

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Which of the following is not correct?

Question 4.

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What happens when methane undergoes combustion in systems A and B respectively?

JEE Main 2023 (Online) 13th April Evening Shift Chemistry - Thermodynamics Question 34 English

Question 5.

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Given

(A)2CO(g)+O2(g)2CO2(g)ΔH10=xkJmol1
(B)C(graphite)+O2(g)CO2(g)ΔH20=ykJmol1

ΔH0 for the reaction

C(graphite)+12O2(g)CO(g) is :

Question 6.

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Which of the following relations are correct?

(A) ΔU=q+pΔV

(B) ΔG=ΔHTΔS

(C) ΔS=qrevT

(D) ΔH=ΔUΔnRT

Choose the most appropriate answer from the options given below :

Question 7.

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Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R

Assertion A : The reduction of a metal oxide is easier if the metal formed is in liquid state than solid state.

Reason R : The value of ΔGΘ becomes more on negative side as entropy is higher in liquid state than solid state.

In the light of the above statements, choose the most appropriate answer from the options given below

Question 8.

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Which of the following relation is not correct?

Question 9.

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ΔG vs T plot for the formation of MgO, involving reaction

2Mg + O2 2MgO, will look like :

Question 10.

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Match List-I with List-II.

List - IList - II
(A)Spontaneous process(I)ΔH<0
(B)Process with ΔP=0, ΔT=0(II)ΔGT,P<0
(C)ΔHreaction(III)Isothermal and isobaric process
(D)Exothermic Process(IV)[Bond energies of molecules in reactants] [Bond energies of product molecules

Choose the correct answer from the options given below :

Great Job! continue working on more practice questions?

Question 1.

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At 25C and 1 atm pressure, the enthalpy of combustion of benzene (I) and acetylene (g) are 3268 kJ mol1 and 1300 kJ mol1, respectively. The change in enthalpy for the reaction 3 C2H2(g) C6H6 (I), is :

Question 2.

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At 25C and 1 atm pressure, the enthalpies of combustion are as given below :

SubstanceH2C (graphite)C2H6(g)
ΔcHΘkJmol1286.0394.01560.0

The enthalpy of formation of ethane is

Question 3.

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The incorrect expression among the following is :

Question 4.

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During which of the following processes, does entropy decrease?

(A) Freezing of water to ice at 0C

(B) Freezing of water to ice at 10C

(C) N2(g) + 3H2(g) 2NH3(g)

(D) Adsorption of CO(g) on lead surface.

(E) Dissolution of NaCl in water

Choose the correct answer from the options given below :

Question 5.

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For a reaction,
4M(s) + nO2(g) 2M2On(s)
the free energy change is plotted as a functionof temperature. The temperature below whichthe oxide is stable could be inferred from theplot as the point at which :

Question 6.

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Lattice enthalpy and enthalpy of solution of NaCl are 788 kJ mol–1, and 4 kJ mol–1, respectively.
The hydration enthalpy of NaCl is :

Question 7.

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Five moles of an ideal gas at 1 bar and 298 Kis expanded into vacuum to double the volume.The work done is :

Question 8.

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The process that is NOT endothermic in natureis :

Question 9.

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For one mole of an ideal gas, which of thesestatements must be true?
(a) U and H each depends only on temperature
(b) Compressibility factor z is not equal to 1
(c) CP, m – CV, m = R
(d) dU = CVdT for any process

Question 10.

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The true statement amongst the following is :

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