Which of the following expressions is correct in case of a CsCl unit cell (edge length 'a')?
Question 2.
The correct relationships between unit cell edge length 'a' and radius of sphere 'r' for face-centred and body-centred cubic structures respectively are :
Question 3.
A compound is formed by two elements X and Y. The element Y forms cubic close packed arrangement and those of element X occupy one third of the tetrahedral voids. What is the formula of the compound?
Question 4.
Which of the following represents the lattice structure of A_{0.95} O containing A^{2 +} , A^{3 +} and O^{2 -} ions?
Question 5.
A cubic solid is made up of two elements X and Y. Atoms of X are present on every alternate corner and one at the center of cube. Y is at \left(\frac{1}{3}\right)^{rd} of the total faces. The empirical formula of the compound is :
Question 6.
An element X has a body centred cubic (bcc) structure with a cell edge of 200 pm. The density of the element is 5 g cm-3. The number of atoms present in 300 g of the element X is _______________.
Given : Avogadro constant, NA = 6.0 \times 1023 mol-1.
Question 7.
The incorrect statement about the imperfections in solids is :
Question 8.
Given below are two statements.
Statement I : Frenkel defects are vacancy as well as interstitial defects.
Statement II : Frenkel defect leads to colour in ionic solids due to presence of F-centres.
Choose the most appropriate answer for the statements from the options given below :
Question 9.
Select the correct statements
(A) Crystalline solids have long range order.
(B) Crystalline solids are isotropic
(C) Amorphous solid are sometimes called pseudo solids.
(D) Amorphous solids soften over a range of temperatures.
(E) Amorphous solids have a definite heat of fusion.
Choose the most appropriate answer from the options given below.
Question 10.
The parameters of the unit cell of a substance are a = 2.5, b = 3.0, c = 4.0, \alpha = 90^{\circ}, \beta = 120^{\circ}, \gamma = 90^{\circ}. The crystal system of the substance is :
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Question 1.
Given below are two statements. One is labelled as Assertion A nd the other is labelled as Reason R.
Assertion A : Sharp glass edge becomes smooth on heating it upto its melting point.
Reason R : The viscosity of glass decreases on melting.
Choose the most appropriate answer from the options given below.
Question 2.
A hard substance melts at high temperature and is an insulator in both solid and in molten state. This solid is most likely to be a/an :
Question 3.
In a binary compound, atoms of element A form a hcp structure and those of element M occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound is :
Question 4.
A crystal is made up of metal ions 'M1' and 'M2'and oxide ions. Oxide ions form a ccp latticestructure. The cation 'M1' occupies 50% ofoctahedral voids and the cation 'M2' occupies12.5% of tetrahedral voids of oxide lattice. Theoxidation numbers of 'M1' and 'M2' are,respectively :
Question 5.
An element crystallises in a face-centred cubic (fcc) unit cell with cell edge a. The distancebetween the centres of two nearest octahedral voids in the crystal lattice is :
Question 6.
A diatomic molecule X2 has a body-centred cubic(bcc) structure with a cell edge of 300 pm. Thedensity of the molecule is 6.17 g cm–3. The numberof molecules present in 200 g of X2 is : (Avogadro constant (NA) = 6 \times 1023 mol–1)
Question 7.
Which of the following compounds is likely toshow both Frenkel and Schottky defects in itscrystalline form?
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