JEE Main pBlock Elements Practice Questions With Solutions

Updated By Diksha Sharma on 07 Jan, 2025 21:16

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JEE Main Chemistry pBlock Elements Practice Questions

Question 1.

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Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Both rhombic and monoclinic sulphur exist as S8 while oxygen exists as O2.

Reason (R) : Oxygen forms pฯ€โˆ’pฯ€ multiple bonds with itself and other elements having small size and high electronegativity like C,N, which is not possible for sulphur.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 2.

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On reaction of Lead Sulphide with dilute nitric acid which of the following is not formed?

Question 3.

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Identify the correct statements about p-block elements and their compounds.

(A) Non metals have higher electronegativity than metals.

(B) Non metals have lower ionisation enthalpy than metals.

(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.

(D) The non-metal oxides are generally basic in nature.

(E) The metal oxides are generally acidic or neutral in nature.

Choose the correct answer from the options given below :

Question 4.

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Identify the incorrect statements about group 15 elements :

(A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.

(B) The common oxidation states of these elements are โˆ’3,+3 and +5.

(C) Nitrogen has unique ability to form pฯ€โˆ’pฯ€ multiple bonds.

(D) The stability of +5 oxidation states increases down the group.

(E) Nitrogen shows a maximum covalency of 6.

Choose the correct answer from the options given below :

Question 5.

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In qualitative test for identification of presence of phosphorous, the compound is heated with an oxidising agent. Which is further treated with nitric acid and ammonium molybdate respectively. The yellow coloured precipitate obtained is :

Question 6.

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Give below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: The stability order of +1 oxidation state of Ga, In and Tl is Ga < In < Tl.

Reason R: The inert pair effect stabilizes the lower oxidation state down the group.

In the light of the above statements, choose the correct answer from the options given below:

Question 7.

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Among the following halogens

F2,Cl2,Br2ย andย I2

Which can undergo disproportionation reactions?

Question 8.

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Evaluate the following statements related to group 14 elements for their correctness.

(A) Covalent radius decreases down the group from C to Pb in a regular manner.

(B) Electronegativity decreases from C to Pb down the group gradually.

(C) Maximum covalance of C is 4 whereas other elements can expand their covalance due to presence of d orbitals.

(D) Heavier elements do not form pฯ€โˆ’pฯ€ bonds.

(E) Carbon can exhibit negative oxidation states.

Choose the correct answer from the options given below :

Question 9.

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Given below are two statements :

Statement I : Gallium is used in the manufacturing of thermometers.

Statement II : A thermometer containing gallium is useful for measuring the freezing point (256K) of brine solution.

In the light of the above statements, choose the correct answer from the options given below :

Question 10.

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Which of the following material is not a semiconductor.

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Question 1.

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The correct statements from the following are :

(A) The decreasing order of atomic radii of group 13 elements is Tl>In>Ga>Al>B.

(B) Down the group 13 electronegativity decreases from top to bottom.

(C) Al dissolves in dil. HCl and liberates H2 but conc. HNO3 renders Al passive by forming a protective oxide layer on the surface.

(D) All elements of group 13 exhibits highly stable +1 oxidation state.

(E) Hybridisation of Al in [Al(H2O)6]3+ ion is sp3d2.

Choose the correct answer from the options given below :

Question 2.

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The number of neutrons present in the more abundant isotope of boron is 'x'. Amorphous boron upon heating with air forms a product, in which the oxidation state of boron is 'y'. The value of x+y is _________ .

Question 3.

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Given below are two statements :

Statement (I) : SiO2 and GeO2 are acidic while SnO and PbO are amphoteric in nature.

Statement (II) : Allotropic forms of carbon are due to property of catenation and pฯ€โˆ’dฯ€ bond formation.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 4.

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The strongest reducing agent among the following is :

Question 5.

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Given below are two statements:

Statement I : Group 13 trivalent halides get easily hydrolyzed by water due to their covalent nature.

Statement II : AlCl3 upon hydrolysis in acidified aqueous solution forms octahedral [Al(H2O)6]3+ ion.

In the light of the above statements, choose the correct answer from the options given below :

Question 6.

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Given below are two statements:

Statement I : S8 solid undergoes disproportionation reaction under alkaline conditions to form S2โˆ’ and S2O32โˆ’.

Statement II : ClO4โˆ’ can undergo disproportionation reaction under acidic condition.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 7.

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Choose the correct statements from the following

A. All group 16 elements form oxides of general formula EO2 and EO3, where E=S,Se,Te and Po. Both the types of oxides are acidic in nature.

B. TeO2 is an oxidising agent while SO2 is reducing in nature.

C. The reducing property decreases from H2S to H2 Te down the group.

D. The ozone molecule contains five lone pairs of electrons.

Choose the correct answer from the options given below:

Question 8.

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Consider the oxides of group 14 elementsSiO2,GeO2,SnO2,PbO2,CO and GeO. The amphoteric oxides are

Question 9.

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The compound that is white in color is

Question 10.

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Give below are two statements:

Statement - I: Noble gases have very high boiling points.

Statement - II: Noble gases are monoatomic gases. They are held together by strong dispersion forces. Because of this they are liquefied at very low temperature. Hence, they have very high boiling points.

In the light of the above statements, choose the correct answer from the options given below:

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